Collision Model

AP Chemistry· difficulty 2/5

Two Arrhenius plots are compared: reaction A has slope −5000 K, reaction B has slope −10000 K.

1/T ln k A (slope -5000) B (slope -10000)

Which reaction is more sensitive to temperature change, and why?

  • A

    A, because A starts at higher ln k.

  • B

    Both are equally sensitive.

  • C

    A, because shallower slope means stronger T dependence.

  • D

    B, because steeper |slope| means larger Eₐ.

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Explanation

Slope = −Eₐ/R; steeper (more negative) slope means larger Eₐ, so k changes more dramatically with T. B is more T-sensitive.

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