Collision Model

AP Chemistry· difficulty 3/5

Maxwell–Boltzmann curves at two temperatures (T2 > T1) are overlaid; a vertical line marks Ea.

Ea T1 T2 > T1 Kinetic energy

Comparing the Maxwell–Boltzmann distributions at T1 and T2 (T2 > T1), the fraction of molecules with KE > Ea:

  • A

    Decreases at higher T

  • B

    Is greater at T2 than T1

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  • C

    Is zero unless catalyst is present

  • D

    Is the same at both T

Explanation

Higher T flattens and broadens the distribution; more molecules have KE > Ea, so reaction rate increases.

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