Elemental Composition of Pure Substances

AP Chemistry· difficulty 3/5

A 9.0 g sample of an unknown hydrocarbon is burned, producing 27.5 g of CO₂ and 13.5 g of H₂O. The empirical formula has approximate ratio (C : H)

  • A

    1 : 1

  • B

    2 : 5

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  • C

    1 : 3

  • D

    1 : 2

Explanation

n(C) = 27.5/44 = 0.625 mol; n(H) = 2(13.5)/18 = 1.5 mol. Ratio C:H = 0.625 : 1.5 = 1 : 2.4 ≈ 2 : 5 (close to C₂H₅ → C₄H₁₀, butane).

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