AP Chemistry · Topic 1.3

Elemental Composition of Pure Substances Practice

Part of Atomic Structure and Properties.(SPQ-2.A)

Practice questions

11

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Sample questions

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  1. Sample 1difficulty 1/5

    Which is a compound (not an element)?

    • A

      He

    • B

      Au

    • C

      O₂

    • D

      H₂O

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    Why

    H₂O contains two different elements (compound). He and Au are elements; O₂ is an elemental molecule (just one element).

  2. Sample 2difficulty 1/5

    A 0.250 g sample of a hydrocarbon is burned completely in excess O2. The combustion products are passed through a dehydrating tube (gains 0.306 g) followed by a CO2 absorber (gains 0.747 g). The hydrocarbon contains only C and H.

    A separate measurement gives a molar mass of 84 g/mol. What is the molecular formula?

    • A

      C5H10

    • B

      C7H14

    • C

      C6H12

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    • D

      CH2

    Why

    Empirical mass = 14 g/mol. 84/14 = 6 -> C6H12.

  3. Sample 3difficulty 2/5

    Mass percent of solute = (mass solute / mass solution) × 100%. A solution made by dissolving 5 g NaCl in 95 g water has mass %

    • A

      5%

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    • B

      9.5%

    • C

      5.26%

    • D

      50%

    Why

    Mass solution = 5 + 95 = 100 g. Mass % = 5/100 × 100% = 5%.

  4. Sample 4difficulty 2/5

    What is the percent composition by mass of carbon in CO₂?

    • A

      44%

    • B

      12%

    • C

      72.7%

    • D

      27.3%

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    Why

    Mass % C = (12 / 44) × 100% ≈ 27.3%.

  5. Sample 5difficulty 2/5

    A 0.250 g sample of a hydrocarbon is burned completely in excess O2. The combustion products are passed through a dehydrating tube (gains 0.306 g) followed by a CO2 absorber (gains 0.747 g). The hydrocarbon contains only C and H.

    furnace H2O abs +0.306 CO2 abs +0.747 sample 0.250 g hydrocarbon

    What is the empirical formula?

    • A

      CH3

    • B

      CH

    • C

      C2H3

    • D

      CH2

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    Why

    mol C = 0.747/44.01 = 0.01698; mass C = 0.2039 g. mol H = (0.306/18.02)*2 = 0.03396; mass H = 0.0342 g. Sum = 0.238 g (consistent with 0.250 within error). Ratio C:H = 0.01698:0.03396 = 1:2 -> CH2.