Heat Capacity and Calorimetry

AP Chemistry· difficulty 3/5

A 1.500 g sample of benzoic acid (deltaU_combustion = -26.43 kJ/g) is burned in a bomb calorimeter, raising the temperature of the bomb + water from 23.55 C to 27.32 C. In a second experiment, a 0.952 g sample of an unknown solid fuel is burned in the same calorimeter, and the temperature rises by 2.41 C.

bomb sample water jacket benzoic acid: 1.500 g, dT=3.77 C

What is the heat capacity (calorimeter constant) C_cal of the bomb calorimeter?

  • A

    1.05 kJ/C

  • B

    26.43 kJ/C

  • C

    10.51 kJ/C

    check_circle
  • D

    39.65 kJ/C

Explanation

Heat from benzoic acid = 1.500 * 26.43 = 39.65 kJ. C_cal = q / deltaT = 39.65 / 3.77 = 10.51 kJ/C.

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