Buffer Capacity

AP Chemistry· difficulty 4/5

To 1.0 L of buffer (0.20 M acetic acid / 0.20 M acetate), 0.010 mol HCl is added.

Before HCl: [HA]=0.20, [A⁻]=0.20 Add 0.010 mol HCl (1 L) After: [HA]=0.21, [A⁻]=0.19 pKa = 4.74

What is the new pH?

  • A

    5.00

  • B

    4.50

  • C

    4.74

  • D

    4.70

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Explanation

pH = 4.74 + log(0.19/0.21) = 4.74 + (-0.044) = 4.70.

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