Collision Model

AP Chemistry· difficulty 4/5

Doubling the absolute temperature of a reaction with Ea=50E_a = 50 kJ/mol from 300 K to 600 K changes the rate constant by approximately

  • A

    Decreases by half

  • B

    A factor of about 2.7×1042.7 \times 10^4

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  • C

    A factor of 2

  • D

    No change

Explanation

k₂/k₁ = exp[Ea/R · (1/T₁ - 1/T₂)] = exp[50000/8.314 · (1/300 - 1/600)] = exp[6014 · 0.001667] = exp(10.02) ≈ 2.25e4.

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