Cell Potential Under Nonstandard Conditions

AP Chemistry· difficulty 4/5

Zn|Zn²⁺ || Cu²⁺|Cu cell; Q = [Zn²⁺]/[Cu²⁺].

[Cu²⁺]/[Zn²⁺] E_cell E rises as ratio rises

Increasing [Cu²⁺] (decreasing Q) does what to E_cell?

  • A

    Reverses cell polarity

  • B

    Decreases E_cell below E°

  • C

    Increases E_cell above E°

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  • D

    Has no effect

Explanation

Smaller Q → ln Q < 0 → -(RT/nF)ln Q > 0, raising E above E°cell.

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