Electrolysis and Faraday's Law

AP Chemistry· difficulty 3/5

A solution containing equal concentrations of Cu²⁺, Ag⁺, and Zn²⁺ is electrolyzed at low current.

cathode solution: Cu²⁺ +0.34, Ag⁺ +0.80, Zn²⁺ -0.76

Which cation is preferentially reduced first at the cathode?

  • A

    Zn²⁺

  • B

    Ag⁺ (highest E°)

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  • C

    Cu²⁺

  • D

    All three plate simultaneously

Explanation

The cation with the most positive reduction potential is reduced first; Ag⁺ at +0.80 V plates before Cu²⁺ or Zn²⁺.

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