Cell Potential Under Nonstandard Conditions

AP Chemistry· difficulty 4/5

A concentration cell uses identical Cu electrodes in Cu²⁺ solutions of different concentrations.

Cu Cu [Cu²⁺]=0.10 [Cu²⁺]=1.0

In this concentration cell, which electrode is the cathode?

  • A

    Both are simultaneously cathode

  • B

    Neither, since same metal

  • C

    The Cu in 0.10 M Cu²⁺ (less concentrated)

  • D

    The Cu in 1.0 M Cu²⁺ (more concentrated)

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Explanation

The system minimizes ΔG by reducing Cu²⁺ in the more concentrated half-cell, so that side is the cathode.

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