Heat Capacity and Calorimetry

AP Chemistry· difficulty 2/5

A coffee-cup calorimeter consists of an insulated polystyrene cup containing water and a thermometer, open to the air.

T water styrofoam cup

Which assumption is fundamental to using a coffee-cup calorimeter to measure ΔH?

  • A

    The water boils during the reaction

  • B

    No heat is absorbed by the water

  • C

    The reaction occurs at constant volume

  • D

    The reaction occurs at constant atmospheric pressure

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Explanation

A coffee-cup calorimeter is open to the atmosphere, so q_p = ΔH (constant-pressure calorimetry).

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