AP Chemistry · Topic 9.6

Coupled Reactions Practice

Part of Applications of Thermodynamics.(ENE-5.C)

Practice questions

3

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Sample questions

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  1. Sample 1difficulty 4/5

    A→B ΔG=+10 C→D ΔG=-25 coupled: A+C → B+D ΔG_total = ?

    What is ΔG for the coupled reaction?

    • A

      0 kJ

    • B

      -15 kJ

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    • C

      +35 kJ

    • D

      +15 kJ

    Why

    ΔG_total = (+10) + (-25) = -15 kJ; the net reaction is spontaneous when coupled.

  2. Sample 2difficulty 4/5

    ATP hydrolysis (ΔG° ≈ −31 kJ/mol) drives many non-spontaneous reactions in cells via

    • A

      Heat transfer only

    • B

      Coupling — sum of ΔG's becomes negative

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    • C

      Photolysis

    • D

      Catalysis without thermodynamics

    Why

    Energetic coupling: a strongly negative ΔG reaction shares its drop with a non-spontaneous one.

  3. Sample 3difficulty 4/5

    A non-spontaneous reaction with ΔG = +30 kJ can be driven if coupled to a reaction with

    • A

      ΔH = 0

    • B

      ΔS = 0

    • C

      ΔG = −50 kJ

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    • D

      ΔG = +50 kJ

    Why

    Sum must be negative. +30 + (−50) = −20 kJ; coupled ΔG of −50 drives it.