AP Chemistry · Topic 5.1

Reaction Rates Practice

Part of Kinetics.(TRA-3.A)

Practice questions

6

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Sample questions

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  1. Sample 1difficulty 2/5

    Average rate (chord)

    The dashed line shows the average rate from t=0 to t=tf. As the time interval shrinks toward zero, the chord slope approaches:

    • A

      The rate constant k

    • B

      Infinity

    • C

      The instantaneous rate

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    • D

      Zero

    Why

    Limit of average rate as Δt -> 0 is the instantaneous rate at that time.

  2. Sample 2difficulty 2/5

    Which is true for a reaction with rate decreasing over time?

    • A

      Rate increases as products form

    • B

      Average rate equals initial rate

    • C

      Instantaneous rate at t=0 is largest

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    • D

      Rate is independent of concentration

    Why

    Reactant concentration is highest at t=0, so initial instantaneous rate is largest.

  3. Sample 3difficulty 2/5

    A common technique to follow a gas-producing reaction's rate is

    • A

      Measure color of catalyst

    • B

      Measure pH continuously

    • C

      Measure mass loss or gas volume vs time

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    • D

      Measure ΔH directly

    Why

    For gas products, monitor mass decrease (open container) or gas volume produced over time.

  4. Sample 4difficulty 2/5

    For 2 N2O5 -> 4 NO2 + O2, [N2O5] is consumed twice as fast (in moles) as O2 is produced.

    [N2O5] [NO2]

    The rate of formation of NO2 equals what multiple of the rate of disappearance of N2O5?

    • A

    • B

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    • C

    • D

      1/2×

    Why

    Stoichiometry: 2 N2O5 -> 4 NO2. So [NO2] forms at twice the rate that [N2O5] is consumed.

  5. Sample 5difficulty 2/5

    For 2 NO₂ → 2 NO + O₂, if [NO₂] decreases at 0.080 M/s, the rate of formation of O₂ is

    • A

      0.080 M/s

    • B

      0.020 M/s

    • C

      0.040 M/s

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    • D

      0.160 M/s

    Why

    Rate = (1/2)·d[NO₂]/dt = d[O₂]/dt → O₂ rate = 0.040 M/s.