Galvanic (Voltaic) and Electrolytic Cells

AP Chemistry· difficulty 1/5

A student constructs a Zn|Zn^2+(1.0 M) || Cu^2+(1.0 M)|Cu galvanic cell with a KNO3 salt bridge and reads the voltage with a high-impedance voltmeter. Standard reduction potentials: Cu^2+/Cu = +0.34 V; Zn^2+/Zn = -0.76 V. The measured cell voltage at 25 C is 1.08 V.

Zn Cu KNO3 bridge e- flow Zn->Cu

What is the role of the KNO3 salt bridge?

  • A

    completes the external electron pathway

  • B

    provides Cu^2+ ions to the cathode

  • C

    maintains charge neutrality by allowing ion flow between half-cells, enabling sustained current

    check_circle
  • D

    increases the cell potential beyond E^o

Explanation

The salt bridge transports K+ toward the cathode and NO3- toward the anode to balance charge as electrons flow through the wire.

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