AP Chemistry · Topic 9.7
Galvanic (Voltaic) and Electrolytic Cells Practice
Part of Applications of Thermodynamics.(ENE-6.A)
Practice questions
17
Sample questions
5 of 17 — sign in to practice the rest with adaptive difficulty and mastery tracking.
Sample 1difficulty 1/5
A student constructs a Zn|Zn^2+(1.0 M) || Cu^2+(1.0 M)|Cu galvanic cell with a KNO3 salt bridge and reads the voltage with a high-impedance voltmeter. Standard reduction potentials: Cu^2+/Cu = +0.34 V; Zn^2+/Zn = -0.76 V. The measured cell voltage at 25 C is 1.08 V.
What is the role of the KNO3 salt bridge?
- A
completes the external electron pathway
- B
provides Cu^2+ ions to the cathode
- Ccheck_circle
maintains charge neutrality by allowing ion flow between half-cells, enabling sustained current
- D
increases the cell potential beyond E^o
Why
The salt bridge transports K+ toward the cathode and NO3- toward the anode to balance charge as electrons flow through the wire.
- A
Sample 2difficulty 2/5
What is the role of the salt bridge in a galvanic cell?
- Acheck_circle
Maintain electrical neutrality by ion flow between half-cells
- B
Provide chemical energy to the cell
- C
Catalyze the redox reaction
- D
Allow electrons to flow between half-cells
Why
The salt bridge supplies spectator ions (cations to the cathode side, anions to the anode side) to balance charge so the cell can keep operating.
- A
Sample 3difficulty 2/5
In standard cell-line notation, what does the double vertical bar (||) represent?
- A
An electrode boundary
- Bcheck_circle
The salt bridge separating the two half-cells
- C
An electron flow direction
- D
The voltmeter
Why
Single | denotes a phase boundary; double || denotes the salt bridge or porous separator between the two half-cells.
- A
Sample 4difficulty 2/5
A working battery is a
- Acheck_circle
Galvanic cell
- B
Catalyst
- C
Capacitor
- D
Electrolytic cell
Why
Spontaneous redox produces current (galvanic). Recharging is electrolysis (forced).
- A
Sample 5difficulty 2/5
In a galvanic (voltaic) cell, electrons flow externally in which direction?
- A
From anode to cathode through the salt bridge
- B
Electrons do not flow externally
- C
From cathode to anode through the wire
- Dcheck_circle
From anode to cathode through the wire
Why
Oxidation at the anode releases electrons, which travel through the external wire to the cathode where reduction occurs.
- A