AP Chemistry · Topic 9.7

Galvanic (Voltaic) and Electrolytic Cells Practice

Part of Applications of Thermodynamics.(ENE-6.A)

Practice questions

17

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Sample questions

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  1. Sample 1difficulty 1/5

    A student constructs a Zn|Zn^2+(1.0 M) || Cu^2+(1.0 M)|Cu galvanic cell with a KNO3 salt bridge and reads the voltage with a high-impedance voltmeter. Standard reduction potentials: Cu^2+/Cu = +0.34 V; Zn^2+/Zn = -0.76 V. The measured cell voltage at 25 C is 1.08 V.

    Zn Cu KNO3 bridge e- flow Zn->Cu

    What is the role of the KNO3 salt bridge?

    • A

      completes the external electron pathway

    • B

      provides Cu^2+ ions to the cathode

    • C

      maintains charge neutrality by allowing ion flow between half-cells, enabling sustained current

      check_circle
    • D

      increases the cell potential beyond E^o

    Why

    The salt bridge transports K+ toward the cathode and NO3- toward the anode to balance charge as electrons flow through the wire.

  2. Sample 2difficulty 2/5

    KNO₃ bridge NO₃⁻ K⁺

    What is the role of the salt bridge in a galvanic cell?

    • A

      Maintain electrical neutrality by ion flow between half-cells

      check_circle
    • B

      Provide chemical energy to the cell

    • C

      Catalyze the redox reaction

    • D

      Allow electrons to flow between half-cells

    Why

    The salt bridge supplies spectator ions (cations to the cathode side, anions to the anode side) to balance charge so the cell can keep operating.

  3. Sample 3difficulty 2/5

    Zn(s) | Zn²⁺(aq) || Cu²⁺(aq) | Cu(s) anode cathode salt bridge

    In standard cell-line notation, what does the double vertical bar (||) represent?

    • A

      An electrode boundary

    • B

      The salt bridge separating the two half-cells

      check_circle
    • C

      An electron flow direction

    • D

      The voltmeter

    Why

    Single | denotes a phase boundary; double || denotes the salt bridge or porous separator between the two half-cells.

  4. Sample 4difficulty 2/5

    A working battery is a

    • A

      Galvanic cell

      check_circle
    • B

      Catalyst

    • C

      Capacitor

    • D

      Electrolytic cell

    Why

    Spontaneous redox produces current (galvanic). Recharging is electrolysis (forced).

  5. Sample 5difficulty 2/5

    + Zn anode Cu cathode e⁻ flow ↑

    In a galvanic (voltaic) cell, electrons flow externally in which direction?

    • A

      From anode to cathode through the salt bridge

    • B

      Electrons do not flow externally

    • C

      From cathode to anode through the wire

    • D

      From anode to cathode through the wire

      check_circle

    Why

    Oxidation at the anode releases electrons, which travel through the external wire to the cathode where reduction occurs.