Collision Model

AP Chemistry· difficulty 4/5

For a reaction at four temperatures, k values are determined and ln k is plotted vs 1/T. The slope of the best-fit line is −1.20×10⁴ K.

1/T (K⁻¹) ln k slope = −Eₐ/R = −1.20×10⁴ K

What is the activation energy Eₐ?

  • A

    8.31 kJ/mol

  • B

    99.7 kJ/mol

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  • C

    144 kJ/mol

  • D

    12.0 kJ/mol

Explanation

Eₐ = −R(slope) = −(8.314 J/mol·K)(−1.20×10⁴ K) = 9.98×10⁴ J/mol ≈ 99.7 kJ/mol.

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