Reaction Energy Profile

AP Chemistry· difficulty 2/5

A reaction-energy diagram with two transition states (peaks) is shown.

progress E reactants products TS1 TS2

Which step is rate determining?

  • A

    The second step (TS2).

  • B

    The first step (TS1, higher peak).

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  • C

    Whichever has lower Eₐ.

  • D

    The exothermic step.

Explanation

The slow (rate-determining) step is the one with the highest activation barrier. Here TS1 is taller, so step 1 is rate-determining.

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