AP Chemistry · Topic 5.6

Reaction Energy Profile Practice

Part of Kinetics.(TRA-4.C)

Practice questions

12

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Sample questions

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  1. Sample 1difficulty 1/5

    ?

    The marked point at the peak of the energy profile represents the:

    • A

      Final product

    • B

      Transition state (activated complex)

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    • C

      Intermediate

    • D

      Catalyst

    Why

    The peak corresponds to the highest-energy structure along the reaction path: the transition state.

  2. Sample 2difficulty 2/5

    A reaction-energy diagram with two transition states (peaks) is shown.

    progress E reactants products TS1 TS2

    Which step is rate determining?

    • A

      The second step (TS2).

    • B

      The first step (TS1, higher peak).

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    • C

      Whichever has lower Eₐ.

    • D

      The exothermic step.

    Why

    The slow (rate-determining) step is the one with the highest activation barrier. Here TS1 is taller, so step 1 is rate-determining.

  3. Sample 3difficulty 2/5

    The energy profile of a one-step reaction is shown.

    Ea Reaction progress E

    On the energy profile diagram, the activation energy Ea is best described as:

    • A

      Total energy of products

    • B

      Difference between reactants and products

    • C

      Energy from reactants to transition state peak

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    • D

      Energy from products to peak

    Why

    Ea is the energy required to reach the transition state from reactants.

  4. Sample 4difficulty 2/5

    An energy profile shows products at lower energy than reactants.

    Reaction progress

    The reaction depicted is:

    • A

      Reversible only above 0 K

    • B

      Thermoneutral

    • C

      Exothermic (products lower than reactants)

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    • D

      Endothermic

    Why

    Products are lower in energy than reactants, indicating heat is released — exothermic.

  5. Sample 5difficulty 2/5

    On the diagram, Ea(fwd) = 140 kJ/mol and Ea(rev) = 80 kJ/mol.

    Ea(fwd)=140 Ea(rev)=80

    What is ΔH for the forward reaction?

    • A

      -220 kJ/mol

    • B

      -60 kJ/mol

    • C

      +60 kJ/mol

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    • D

      +220 kJ/mol

    Why

    ΔH = Ea(fwd) - Ea(rev) = 140 - 80 = +60 kJ/mol (endothermic).