Mass Spectroscopy of Elements

AP Chemistry· difficulty 3/5

A mass spectrometer measures the relative abundances of isotopes of a Group 14 element. Two peaks appear at m/z = 28 (92.2%) and m/z = 29 (4.7%) and a small peak at m/z = 30 (3.1%).

m/z 28 (92.2%) 29 (4.7%) 30 (3.1%)

What is the average atomic mass and identity of the element?

  • A

    27.98 amu, aluminum

  • B

    29.00 amu, phosphorus

  • C

    28.50 amu, silicon

  • D

    28.11 amu, silicon

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Explanation

Avg = (28)(0.922) + (29)(0.047) + (30)(0.031) = 25.82 + 1.363 + 0.93 = 28.11 amu. This matches silicon (28.09 amu).

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