Reaction Quotient and Equilibrium Constant

AP Chemistry· difficulty 3/5

For N₂ + 3H₂ ⇌ 2NH₃ (Kc = 0.50 at T), a vessel contains [N₂] = 1.0 M, [H₂] = 1.0 M, [NH₃] = 1.0 M.

Kc = 0.50 [N₂]=[H₂]=[NH₃]=1.0 M Find Q, predict shift

What is Q, and which way does the reaction shift?

  • A

    Q = 0.50; system at equilibrium.

  • B

    Q = 2.0; shifts left.

  • C

    Q = 1.0; shifts right.

  • D

    Q = 1.0; shifts left (reverse).

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Explanation

Q = [NH₃]²/([N₂][H₂]³) = 1²/(1·1³) = 1.0. Q > Kc, so reverse.

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