AP Chemistry · Topic 7.3

Reaction Quotient and Equilibrium Constant Practice

Part of Equilibrium.(TRA-7.A)

Practice questions

6

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Sample questions

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  1. Sample 1difficulty 2/5

    For aA + bB ⇌ cC + dD, K =

    • A

      [A]^a[B]^b / [C]^c[D]^d

    • B

      abK − cd

    • C

      [C]^c[D]^d / [A]^a[B]^b

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    • D

      ([A]+[B]) / ([C]+[D])

    Why

    Products over reactants, each raised to its stoichiometric coefficient.

  2. Sample 2difficulty 2/5

    Q is computed

    • A

      Only at equilibrium

    • B

      Only at standard state

    • C

      Only with K

    • D

      At any moment using current concentrations

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    Why

    Q is the same expression as K, but with current (not necessarily equilibrium) values.

  3. Sample 3difficulty 2/5

    Pure solids and pure liquids are excluded from K expressions.

    CaCO3(s) <-> CaO(s) + CO2(g) K = ? (only gases / aqueous in K)

    What is the correct equilibrium expression?

    • A

      K = [CO2]

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    • B

      K = [CaO][CO2]/[CaCO3]

    • C

      K = [CO2]/[CaCO3]

    • D

      K = [CaO][CO2]

    Why

    Pure solids do not appear in K. Only the gaseous CO2 contributes: K = [CO2] (or Kp = P_CO2).

  4. Sample 4difficulty 3/5

    For N₂ + 3H₂ ⇌ 2NH₃ (Kc = 0.50 at T), a vessel contains [N₂] = 1.0 M, [H₂] = 1.0 M, [NH₃] = 1.0 M.

    Kc = 0.50 [N₂]=[H₂]=[NH₃]=1.0 M Find Q, predict shift

    What is Q, and which way does the reaction shift?

    • A

      Q = 0.50; system at equilibrium.

    • B

      Q = 2.0; shifts left.

    • C

      Q = 1.0; shifts right.

    • D

      Q = 1.0; shifts left (reverse).

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    Why

    Q = [NH₃]²/([N₂][H₂]³) = 1²/(1·1³) = 1.0. Q > Kc, so reverse.

  5. Sample 5difficulty 3/5

    For A + B ⇌ C, [A]=0.10, [B]=0.10, [C]=0.05. K = 100. The reaction

    • A

      Is at equilibrium

    • B

      Shifts left

    • C

      Cannot tell

    • D

      Shifts right

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    Why

    Q = 0.05/(0.10·0.10) = 5; 5 < 100 → forward shift.