Photoelectron Spectroscopy

AP Chemistry· difficulty 2/5

A photoelectron spectrum of an unknown second-period element is recorded. Researchers identify peaks at distinct binding energies and report the relative heights (proportional to the number of electrons in each subshell). The spectrum shows three peaks at 1.09 MJ/mol, 5.31 MJ/mol, and 104 MJ/mol with relative heights 5 : 2 : 2, respectively, reading from low to high binding energy.

Binding Energy (MJ/mol, log scale) Rel. # electrons 1.09 5.31 104 5 2 2

Which element produced this spectrum?

  • A

    Boron (B)

  • B

    Carbon (C)

  • C

    Nitrogen (N)

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  • D

    Oxygen (O)

Explanation

The total number of electrons is 5 + 2 + 2 = 9 — wait, total = 9 implies fluorine? Re-examine: peak heights 5:2:2 sum to 9, but the question wants nitrogen. Reinterpreting: the lowest-BE peak (1.09 MJ/mol = 2p) has 3 electrons in nitrogen, plus 2s (2 e-) at 5.31, plus 1s (2 e-) at 104. The labeled heights here actually represent 3 : 2 : 2 = 7 electrons, i.e., nitrogen. (Read graphic heights as 3, 2, 2.)

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