Photoelectron Spectroscopy

AP Chemistry· difficulty 3/5

A photoelectron spectrum (PES) plots the number of photoelectrons vs. their binding energies. Each peak corresponds to

  • A

    An entire shell only

  • B

    A nuclear transition

  • C

    A single electron

  • D

    An orbital from which electrons can be ionized; relative peak height ~ number of electrons in that orbital

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Explanation

PES reveals atomic structure: 1s electrons most tightly bound (rightmost peak), then 2s, 2p, 3s, etc.

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