Elemental Composition of Pure Substances

AP Chemistry· difficulty 4/5

Combustion of 5.000 g of a hydrocarbon produces 15.40 g of CO2CO_2 and 7.886 g of H2OH_2O. What is the empirical formula?

  • A

    C2H5C_2H_5

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  • B

    C4H9C_4H_9

  • C

    C3H7C_3H_7

  • D

    CH3CH_3

Explanation

Mol C = 15.40/44.01=0.349915.40/44.01 = 0.3499. Mol H = 27.886/18.02=0.87532 \cdot 7.886/18.02 = 0.8753. Ratio H:C = 0.8753/0.3499=2.500.8753/0.3499 = 2.50, i.e. C:H = 2:5. The empirical formula is C2H5C_2H_5.

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