Cell Potential and Free Energy

AP Chemistry· difficulty 3/5

The relationship between standard free energy and cell potential is shown.

ΔG° < 0 E°cell > 0 spontaneous ΔG° > 0 E°cell < 0 non-spont. ΔG° = -nFE°cell

A galvanic cell has E°cell = +1.10 V and n = 2. What is the sign of ΔG°?

  • A

    Negative; the cell reaction is spontaneous

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  • B

    Cannot be determined without T

  • C

    Positive; the cell reaction is non-spontaneous

  • D

    Zero; system is at equilibrium

Explanation

ΔG° = -nFE°cell. With n=2 and E° positive, ΔG° is negative, indicating spontaneity.

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