Periodic Trends

AP Chemistry· difficulty 3/5

Na 186 pm Na+ 102 pm

Why is Na+ much smaller than Na?

  • A

    The cation has a larger radius normally

  • B

    Loss of an electron decreases the nuclear charge

  • C

    An additional electron shell is removed

  • D

    Loss of the 3s valence electron leaves only the smaller n=2 shell as outermost; Zeff per remaining electron is higher

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Explanation

Removing the lone 3s electron leaves Na+ with only 10 electrons in n=2; the unchanged +11 nucleus pulls them in tightly.

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