Periodic Trends

AP Chemistry· difficulty 3/5

The graph plots first ionization energy across period 2. Two anomalies are highlighted in red, where IE1 drops slightly compared to the previous element.

Period 2 elements IE1 (kJ/mol) Li Be B C N O F Ne

The dip at boron (compared to Be) and oxygen (compared to N) is best explained by:

  • A

    Removal of an electron from a higher-energy 2p orbital (B) and from a paired 2p orbital (O)

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  • B

    Differences in atomic radius only

  • C

    Increased shielding by core electrons

  • D

    A change in nuclear charge magnitude

Explanation

Boron's electron removed comes from 2p (higher energy than Be's 2s); oxygen's first paired 2p electron experiences extra repulsion making it easier to remove.

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