Enzyme Catalysis

AP Biology· difficulty 3/5

A third trial added a putative inhibitor at fixed concentration to catalase. Reaction rate was measured across the same range of [H2O2]. Vmax of the uninhibited enzyme (4.1 mL/s) was unchanged, but more substrate was needed to approach Vmax.

[H2O2] (mM) Rate no inhibitor + inhibitor Vmax

The data are most consistent with which type of inhibition?

  • A

    Noncompetitive inhibition

  • B

    Irreversible denaturation

  • C

    Allosteric activation

  • D

    Competitive inhibition

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Explanation

Competitive inhibitors raise the apparent Km (more substrate needed) but Vmax can still be reached at high [S]. Noncompetitive inhibitors lower Vmax.

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