AP Chemistry · Topic 8.3

Weak Acid and Base Equilibria Practice

Part of Acids and Bases.(SAP-9.C)

Practice questions

27

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Sample questions

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  1. Sample 1difficulty 2/5

    The pH of 0.10 M HA is 3.0.

    [HA]₀ = 0.10 M pH = 3.00 Find Ka

    What is Ka of HA?

    • A

      1.0×10⁻¹

    • B

      1.0×10⁻⁵

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    • C

      1.0×10⁻³

    • D

      1.0×10⁻⁷

    Why

    [H⁺] = 10⁻³ M = x. Ka ≈ x²/[HA]₀ = (10⁻³)²/0.10 = 10⁻⁶/10⁻¹ = 10⁻⁵.

  2. Sample 2difficulty 3/5

    NaF pH 8 NH4Cl pH 5 KNO3 pH 7

    Which best explains the pH of the NaF solution?

    • A

      NaF is a strong base

    • B

      F- is a strong acid

    • C

      Na+ accepts H+ from water

    • D

      F- is the conjugate base of HF and hydrolyzes water

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    Why

    NaF is the salt of a strong base (NaOH) and weak acid (HF). The fluoride ion (a weak base) abstracts a proton from water, giving slightly basic pH > 7.

  3. Sample 3difficulty 3/5

    Percent ionization of a weak acid generally

    • A

      Increases as concentration increases

    • B

      Independent of concentration

    • C

      Decreases as concentration increases

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    • D

      Always 100%

    Why

    Diluting shifts equilibrium toward more ionization (Le Chatelier on increased moles of solute particles).

  4. Sample 4difficulty 3/5

    For a diprotic acid H₂A, generally

    • A

      K_a1 < K_a2

    • B

      K_a1 ≫ K_a2

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    • C

      K_a1 = K_a2

    • D

      Both are zero

    Why

    Removing the first proton is much easier than removing the second from the resulting anion.

  5. Sample 5difficulty 3/5

    For NH₃ + H₂O ⇌ NH₄⁺ + OH⁻, K_b =

    • A

      [NH₄⁺][OH⁻]/[NH₃]

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    • B

      [NH₃]/[NH₄⁺][OH⁻]

    • C

      [OH⁻]/[NH₃]

    • D

      [NH₄⁺]/[OH⁻]

    Why

    Standard expression for base dissociation; water omitted.