AP Chemistry · Topic 7.7

Calculating Equilibrium Concentrations Practice

Part of Equilibrium.(TRA-7.E)

Practice questions

14

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Sample questions

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  1. Sample 1difficulty 3/5

    For A(g) <-> B(g) + C(g), Kc = 0.040 with the ICE table shown.

    ICE A B C I C E 1.0 0 0 -x +x +x 1.0-x x x

    If x is small relative to 1.0, what is x approximately?

    • A

      0.040

    • B

      0.50

    • C

      0.20

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    • D

      0.0040

    Why

    Kc ~ x*x/1.0 = x^2 = 0.040, so x = sqrt(0.040) = 0.20 (small-x approximation).

  2. Sample 2difficulty 3/5

    For N2O4(g) <-> 2 NO2(g), at equilibrium [NO2] = 0.20 M.

    ICE N2O4 NO2 I 0.50 0 C -x +2x E 0.50-x 2x

    What is [N2O4] at equilibrium?

    • A

      0.10 M

    • B

      0.50 M

    • C

      0.20 M

    • D

      0.40 M

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    Why

    2x = 0.20, so x = 0.10. [N2O4] = 0.50 - 0.10 = 0.40 M.

  3. Sample 3difficulty 3/5

    For A ⇌ 2B with [A]₀ = 1.0 M and [B]₀ = 0, the equilibrium expressions are

    • A

      [A] = 1.0 − x; [B] = 2x

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    • B

      [A] = 1.0; [B] = x

    • C

      [A] = 1.0 − 2x; [B] = x

    • D

      [A] = 1.0 + x; [B] = 2x

    Why

    Stoichiometry: A loses x, B gains 2x.

  4. Sample 4difficulty 3/5

    Consider N2(g) + 3 H2(g) <-> 2 NH3(g) starting from the initial concentrations shown.

    ICE N2 H2 NH3 I C E 0.50 1.50 0 -x ? +2x 0.50-x ? 2x

    What value belongs in the H2 "Change" cell of the ICE table?

    • A

      +3x

    • B

      -x

    • C

      -3x

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    • D

      +x

    Why

    Stoichiometry: for every 1 mol N2 consumed, 3 mol H2 are consumed. If N2 changes by -x, then H2 changes by -3x.

  5. Sample 5difficulty 4/5

    A ⇌ B with [A]₀ = 0.50 M and K = 1.0. At equilibrium [B] is

    • A

      0.40 M

    • B

      0.25 M

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    • C

      0.50 M

    • D

      0.10 M

    Why

    K = [B]/[A] = x/(0.50 − x) = 1 → x = 0.25 M.