AP Chemistry · Topic 6.8
Enthalpy of Formation Practice
Part of Thermodynamics.(ENE-3.C)
Practice questions
5
Sample questions
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Sample 1difficulty 1/5
ΔH°_f for O₂(g) at standard state is
- A
Variable
- Bcheck_circle
0
- C
+286 kJ/mol
- D
−286 kJ/mol
Why
Elements in their standard state have ΔH°_f = 0 by definition.
- A
Sample 2difficulty 3/5
ΔH°_rxn equals
- A
Σν_r ΔH°_f − Σν_p ΔH°_f
- B
ΔS° × T
- Ccheck_circle
Σν_p ΔH°_f (products) − Σν_r ΔH°_f (reactants)
- D
−RT ln K
Why
Formation enthalpies: products minus reactants, weighted by stoichiometry.
- A
Sample 3difficulty 3/5
What is ΔH°rxn for the combustion of methane (using values shown)?
- A
-604 kJ
- B
-186 kJ
- C
+890 kJ
- Dcheck_circle
-890 kJ
Why
ΔH°rxn = [(-393) + 2(-286)] - [(-75) + 2(0)] = (-965) - (-75) = -890 kJ.
- A
Sample 4difficulty 3/5
The diagram shows reactants and products related to elements in their standard states via formation enthalpies.
Which formula gives ΔH°rxn from standard enthalpies of formation?
- A
ΣΔHf°(reactants) − ΣΔHf°(products)
- B
ΔHf°(any product alone)
- C
ΣΔHf°(products) + ΣΔHf°(reactants)
- Dcheck_circle
ΣΔHf°(products) − ΣΔHf°(reactants)
Why
By Hess's law applied to the formation cycle, ΔH°rxn = ΣnΔHf°(products) − ΣmΔHf°(reactants).
- A
Sample 5difficulty 4/5
Which has ΔH = 0 by definition?
- A
Br(g)
- B
All compounds
- C
HO(l)
- Dcheck_circle
Br(l) at 25°C, 1 atm (element in standard state)
Why
Element in its standard state has ΔH = 0. For Br that's the liquid; for Hg it's liquid; for I it's solid; etc.
- A