AP Chemistry · Topic 6.8

Enthalpy of Formation Practice

Part of Thermodynamics.(ENE-3.C)

Practice questions

5

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Sample questions

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  1. Sample 1difficulty 1/5

    ΔH°_f for O₂(g) at standard state is

    • A

      Variable

    • B

      0

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    • C

      +286 kJ/mol

    • D

      −286 kJ/mol

    Why

    Elements in their standard state have ΔH°_f = 0 by definition.

  2. Sample 2difficulty 3/5

    ΔH°_rxn equals

    • A

      Σν_r ΔH°_f − Σν_p ΔH°_f

    • B

      ΔS° × T

    • C

      Σν_p ΔH°_f (products) − Σν_r ΔH°_f (reactants)

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    • D

      −RT ln K

    Why

    Formation enthalpies: products minus reactants, weighted by stoichiometry.

  3. Sample 3difficulty 3/5

    CH₄ + 2 O₂ → CO₂ + 2 H₂O ΔHf° (kJ/mol): CH₄ -75 O₂ 0 CO₂ -393 H₂O(l) -286

    What is ΔH°rxn for the combustion of methane (using values shown)?

    • A

      -604 kJ

    • B

      -186 kJ

    • C

      +890 kJ

    • D

      -890 kJ

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    Why

    ΔH°rxn = [(-393) + 2(-286)] - [(-75) + 2(0)] = (-965) - (-75) = -890 kJ.

  4. Sample 4difficulty 3/5

    The diagram shows reactants and products related to elements in their standard states via formation enthalpies.

    elements (0) reactants products ΔH°rxn = ΣΔHf°(prod) − ΣΔHf°(react)

    Which formula gives ΔH°rxn from standard enthalpies of formation?

    • A

      ΣΔHf°(reactants) − ΣΔHf°(products)

    • B

      ΔHf°(any product alone)

    • C

      ΣΔHf°(products) + ΣΔHf°(reactants)

    • D

      ΣΔHf°(products) − ΣΔHf°(reactants)

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    Why

    By Hess's law applied to the formation cycle, ΔH°rxn = ΣnΔHf°(products) − ΣmΔHf°(reactants).

  5. Sample 5difficulty 4/5

    Which has ΔHf°_f^° = 0 by definition?

    • A

      Br2_2(g)

    • B

      All compounds

    • C

      H2_2O(l)

    • D

      Br2_2(l) at 25°C, 1 atm (element in standard state)

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    Why

    Element in its standard state has ΔHf°_f^° = 0. For Br2_2 that's the liquid; for Hg it's liquid; for I2_2 it's solid; etc.