AP Chemistry · Topic 3.11

Spectroscopy and the Electromagnetic Spectrum Practice

Part of Properties of Substances and Mixtures.(SAP-8.A)

Practice questions

2

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Sample questions

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  1. Sample 1difficulty 3/5

    UV-Vis spectroscopy measures absorption of light in the _______ range, used to study _______.

    • A

      infrared; vibrations

    • B

      ultraviolet to visible (~200-800 nm); electronic transitions, often in conjugated systems

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    • C

      radio; nuclear spin

    • D

      X-ray; atoms

    Why

    UV-Vis: electronic transitions (π → π*, n → π*, etc.). IR: bond vibrations. NMR: nuclear spin transitions in magnetic field.

  2. Sample 2difficulty 3/5

    A strong, broad IR absorption near 3300 cm⁻¹ is characteristic of

    • A

      C=O stretch

    • B

      O-H or N-H stretch (hydrogen-bonded)

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    • C

      Aromatic ring

    • D

      C-C stretch

    Why

    H-bonded O-H (alcohols, carboxylic acids) gives broad absorbance ~3200-3500 cm⁻¹. C=O is sharp, near 1700 cm⁻¹.