Acid-Base Titrations

AP Chemistry· difficulty 2/5

A student titrates 25.00 mL of an HCl solution of unknown concentration with standardized 0.1050 M NaOH using phenolphthalein indicator. The endpoint (faint pink) is reached at 23.42 mL of base. A pH probe is used in a parallel run to record the titration curve, which shows a near-vertical jump centered at pH ~7.

pH Volume NaOH (mL) equiv pt 7

What is the concentration of the HCl solution?

  • A

    0.112 M

  • B

    0.0246 M

  • C

    0.0984 M

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  • D

    0.1050 M

Explanation

Moles NaOH = 0.02342 * 0.1050 = 2.459e-3 mol = moles HCl. [HCl] = 2.459e-3 / 0.02500 = 0.0984 M.

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