Concentration Changes Over Time

AP Chemistry· difficulty 3/5

For the decomposition of A, students plot ln[A] vs t and 1/[A] vs t. Only the ln[A] plot gives a straight line.

t (s) ln[A] slope = -0.025 s⁻¹

What is the order of the reaction in A and the value of k?

  • A

    First order, k = 0.025 s⁻¹

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  • B

    First order, k = -0.025 s⁻¹

  • C

    Zero order, k = 0.025 M/s

  • D

    Second order, k = 0.025 M⁻¹s⁻¹

Explanation

Linearity of ln[A] vs t indicates first order. The slope = -k, so k = 0.025 s⁻¹.

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