Introduction to Reaction Mechanisms

AP Chemistry· difficulty 4/5

For the proposed mechanism: (1) NO2_2 + NO2_2 → NO3_3 + NO (slow); (2) NO3_3 + CO → NO2_2 + CO2_2 (fast). The rate law is

  • A

    rate = k[NO2_2]

  • B

    rate = k[NO3_3][CO]

  • C

    rate = k[NO2_2][CO]

  • D

    rate = k[NO2_2]2^2 (slow step rate-determining)

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Explanation

Rate-determining (slow) step controls: rate = k[NO2_2]2^2. CO doesn't appear because it enters only in the fast step.

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