Atomic Structure and Electron Configuration

AP Chemistry· difficulty 4/5

Cr (Z = 24) is best described as

  • A

    [Ar]4s13d5[Ar]\,4s^1\,3d^5 — half-filled d shell stabilization

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  • B

    [Ar]4s03d6[Ar]\,4s^0\,3d^6

  • C

    [Ar]4s23d4[Ar]\,4s^2\,3d^4 — strict aufbau order

  • D

    [Ar]3d6[Ar]\,3d^6 — collapse of 4s subshell

Explanation

Cr breaks aufbau: half-filled 3d⁵ (and full 4s¹) lowers energy via exchange stabilization. Same anomaly in Mo, Cu, Au.

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