Direction of Reversible Reactions

AP Chemistry· difficulty 2/5

For a reaction A(g) <-> B(g) at equilibrium, K = 4.0. A new mixture has [A] = 0.20 M and [B] = 0.10 M.

Q = K Q < K Q > K shifts -> <- shifts more reactants more products

Which direction will the system shift to reach equilibrium?

  • A

    Reverse, because Q = 0.5 < K

  • B

    Forward, because Q = 0.5 < K

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  • C

    No shift, because Q = K

  • D

    Forward, because Q > K

Explanation

Q = [B]/[A] = 0.10/0.20 = 0.5. Since Q < K, the reaction proceeds in the forward direction to make more products.

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