Cell Potential and Free Energy

AP Chemistry· difficulty 3/5

Cu²⁺ + 2e⁻ → Cu E° = +0.34 V Zn²⁺ + 2e⁻ → Zn E° = -0.76 V

+E° -E° Cu²⁺/Cu +0.34 Zn²⁺/Zn -0.76

For the galvanic cell Zn|Zn²⁺ || Cu²⁺|Cu, what is E°cell?

  • A

    +1.10 V

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  • B

    -1.10 V

  • C

    -0.42 V

  • D

    +0.42 V

Explanation

E°cell = E°cathode - E°anode = (+0.34) - (-0.76) = +1.10 V.

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