Types of Chemical Bonds

AP Chemistry· difficulty 3/5

Two diagrams contrast NaCl (Na+ and Cl- ions) with Cl2 (two chlorine atoms sharing a bonding pair of electrons).

Ionic (NaCl) Covalent (Cl2) Na+ Cl- Cl Cl electron transfer electron sharing

Which best distinguishes ionic from covalent bonding?

  • A

    Ionic bonds form between ions (large EN difference); covalent bonds share electrons (small EN difference)

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  • B

    Ionic bonds are weaker than covalent bonds

  • C

    Ionic bonds are always polar covalent

  • D

    Covalent bonds only form between metals

Explanation

A large electronegativity difference (>~1.7) drives complete electron transfer (ionic), whereas similar electronegativities lead to electron sharing (covalent).

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