AP Chemistry · Topic 6.1

Endothermic and Exothermic Processes Practice

Part of Thermodynamics.(ENE-2.A)

Practice questions

7

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Sample questions

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  1. Sample 1difficulty 1/5

    system +q in -q out

    By convention, when heat flows OUT of the system into the surroundings, q is:

    • A

      Equal to ΔS

    • B

      Positive (endothermic)

    • C

      Negative (exothermic)

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    • D

      Always zero

    Why

    Sign convention: q < 0 means the system loses heat (exothermic); q > 0 means it gains heat.

  2. Sample 2difficulty 1/5

    A reaction with ΔH > 0 is

    • A

      Endothermic

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    • B

      Spontaneous

    • C

      Catalyzed

    • D

      Exothermic

    Why

    Positive ΔH = heat absorbed by the system from surroundings.

  3. Sample 3difficulty 1/5

    A student dissolves 5.00 g of NH4NO3 (M = 80.04 g/mol) in 100.0 g of water in a coffee-cup calorimeter. Initial water temperature = 22.0 C. After dissolution and complete mixing, the minimum temperature is 18.6 C. Specific heat of solution = 4.18 J/(g*C). Total mass of solution = 105.0 g. Calorimeter heat capacity is negligible.

    Based on the result, NH4NO3 is the active ingredient in instant cold packs. Why?

    • A

      It is exothermic, releasing heat to keep the pack cold

    • B

      It evaporates instantly

    • C

      Its dissolution is endothermic, so the solution becomes cold by absorbing heat from surroundings

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    • D

      It chemically reacts with hands to feel cool

    Why

    An endothermic dissolution absorbs heat from the surroundings (including a person's body), producing a cooling effect.

  4. Sample 4difficulty 2/5

    In an endothermic process, q for the system is

    • A

      Zero

    • B

      Negative

    • C

      Positive

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    • D

      Undefined

    Why

    Heat flows into system → q_sys > 0.

  5. Sample 5difficulty 2/5

    A hand warmer (oxidation of iron) is

    • A

      Exothermic

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    • B

      Always non-spontaneous

    • C

      Athermal

    • D

      Endothermic

    Why

    Oxidation of Fe releases heat; exothermic, ΔH < 0.