AP Chemistry · Topic 5.11

Catalysis Practice

Part of Kinetics.(TRA-5.E)

Practice questions

13

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Sample questions

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  1. Sample 1difficulty 2/5

    A catalyst increases reaction rate by

    • A

      Raising T

    • B

      Increasing ΔH

    • C

      Shifting equilibrium toward products

    • D

      Lowering Eₐ via an alternate mechanism

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    Why

    Catalysts provide a lower-Eₐ pathway; ΔH and equilibrium are unchanged.

  2. Sample 2difficulty 2/5

    The same reaction is run with and without a catalyst, with k measured at varied T.

    1/T ln k catalyzed (less steep) uncatalyzed (steeper)

    What does the catalyzed line's shallower slope indicate?

    • A

      A lower activation energy.

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    • B

      A first-order reaction.

    • C

      A larger frequency factor only.

    • D

      A higher activation energy.

    Why

    Slope = −Eₐ/R. Shallower (less negative) slope means smaller Eₐ — the catalyst lowers the activation energy.

  3. Sample 3difficulty 2/5

    Two energy profiles for the same reaction are shown: with and without a catalyst.

    No catalyst Catalyst Reaction progress

    What is the effect of a catalyst on the reaction?

    • A

      Raises Ea, slows rate

    • B

      Changes ΔH, shifts equilibrium

    • C

      Lowers Ea but does not change rate

    • D

      Lowers Ea, increases rate

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    Why

    A catalyst provides an alternate pathway with a lower Ea, increasing rate without changing ΔH.

  4. Sample 4difficulty 2/5

    Compared to the uncatalyzed pathway, the catalyzed pathway has:

    • A

      Higher Ea but lower ΔH

    • B

      Same Ea and shifted ΔH

    • C

      Lower Ea and shifted equilibrium

    • D

      Lower Ea but same ΔH and same K_eq

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    Why

    A catalyst speeds both forward and reverse reactions equally; ΔH and K_eq are unchanged.

  5. Sample 5difficulty 2/5

    A heterogeneous catalyst

    • A

      Cannot be regenerated

    • B

      Is in the same phase as reactants

    • C

      Is consumed in the reaction

    • D

      Is in a different phase from reactants

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    Why

    Heterogeneous = different phase (e.g., solid catalyst, gas reactants).

AP Chemistry · 5.11 Catalysis — Practice Questions | Acemy