AP Chemistry · Topic 2.7

VSEPR and Bond Hybridization Practice

Part of Compound Structure and Properties.(SAP-4.C)

Practice questions

46

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Sample questions

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  1. Sample 1difficulty 2/5

    CH₄ has 4 bonded H and no lone pairs on C. Its geometry and bond angle are

    • A

      Trigonal planar, 120°

    • B

      Linear, 180°

    • C

      Square planar, 90°

    • D

      Tetrahedral, 109.5°

      check_circle

    Why

    4 bonded electron pairs arrange tetrahedrally with 109.5° bond angles.

  2. Sample 2difficulty 2/5

    B F F F

    BF3 has a molecular geometry that is:

    • A

      Trigonal pyramidal with 107° angles

    • B

      Trigonal planar with 120° bond angles

      check_circle
    • C

      Tetrahedral with 109.5° angles

    • D

      Bent with 120° angles

    Why

    Boron has 3 bonded atoms and no lone pairs, giving trigonal planar geometry with 120° angles.

  3. Sample 3difficulty 2/5

    180°

    A central atom with 2 bonded atoms and no lone pairs has what geometry?

    • A

      Trigonal planar

    • B

      Bent (e.g., H₂O)

    • C

      Linear (e.g., CO₂)

      check_circle
    • D

      Tetrahedral

    Why

    2 electron domains arrange linearly at 180°. Examples: CO₂, BeCl₂.

  4. Sample 4difficulty 2/5

    Ammonia has nitrogen bonded to three hydrogens with a single lone pair occupying the fourth electron domain.

    N H H H lone pair

    The molecular geometry of NH3 is:

    • A

      Bent

    • B

      Trigonal planar

    • C

      Trigonal pyramidal

      check_circle
    • D

      Tetrahedral

    Why

    With one lone pair and three bonded H atoms, NH3 has tetrahedral electron geometry but trigonal pyramidal molecular shape.

  5. Sample 5difficulty 2/5

    Water is polar because

    • A

      It has polar O-H bonds AND a bent geometry, so dipoles do not cancel

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    • B

      It is symmetric

    • C

      Oxygen is nonpolar

    • D

      Both H-O-H bonds cancel

    Why

    Bent shape means the bond dipoles add to a net molecular dipole pointing toward the O.