AP Chemistry · Topic 2.2

Intramolecular Force and Potential Energy Practice

Part of Compound Structure and Properties.(SAP-3.B)

Practice questions

4

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Sample questions

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  1. Sample 1difficulty 2/5

    For C-C bonds, the order of length (shortest to longest) is

    • A

      C≡C, C=C, C-C

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    • B

      C=C, C≡C, C-C

    • C

      C-C, C=C, C≡C

    • D

      All same

    Why

    Higher bond order → more attraction → shorter bond. Triple < double < single.

  2. Sample 2difficulty 2/5

    For a given pair of atoms, bond strength generally

    • A

      Is unrelated to bond order

    • B

      Is the same regardless

    • C

      Increases as bond order increases (single < double < triple)

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    • D

      Decreases as bond order increases

    Why

    Higher bond order = more shared electron density = stronger and shorter bond.

  3. Sample 3difficulty 3/5

    Bond order Bond length (pm) 3 2 1

    What does this trend show about bond order?

    • A

      As bond order increases, bond length decreases

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    • B

      As bond order increases, bond length increases

    • C

      Bonds of order 1.5 are longest

    • D

      Bond order is unrelated to length

    Why

    Higher bond order pulls atoms closer; triple bonds are shorter than double, which are shorter than single bonds.

  4. Sample 4difficulty 3/5

    Bond energy (kJ/mol) C-C C=C C≡C 347 614 839

    The trend C-C < C=C < C≡C in bond energy implies:

    • A

      Higher bond order means longer, weaker bonds

    • B

      Higher bond order means shorter, stronger bonds

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    • C

      Bond order does not affect bond strength

    • D

      Triple bonds have only sigma overlap

    Why

    Multiple bonds bring atoms closer and concentrate more electron density between them, raising bond energy.